Visible Light-Promoted Synthesis of beta-Keto Sulfoximines from N-Tosyl-Protected Sulfoximidoyl Chlorides

Under visible light, N-tosyl-protected sulfoximidoyl chlorides react with aryl alkynes to give beta-keto sulfoximines. The reaction is characterized by a high functional group tolerance and good yields. It can be improved by the presence of a ruthenium photocatalyst. Air is the source of the ketonic oxygen in the products.