S ep 2 00 2 1 D exciton band and exciton-phonon interaction in a single polymer chain

The excitonic luminescence of an isolated polydiacetylene polymer chain in its monomer matrix is studied by micro-photoluminescence. These chains behave as perfect 1D excitonic systems with the expected 1/ √ E density of states between 5 and 50 K. The temperature dependence of the homogeneous width is quantitatively explained by interaction with longitudinal acoustic phonons of the crystal in the range of temperature explored.