Electrochemical Ce(III)/Ce(IV) interconversion, electrodeposition, and catalytic CO ↔ CO2 interconversion over terpyridine-modified indium tin oxide electrodes

So Jeong Park,Ju Young Maeng,Min Hee Joo,Jun-Gill Kang,Choong Kyun Rhee,Youngku Sohn

Journal of Industrial and Engineering Chemistry（2022）

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摘要

•Thio-terpyridyl derivatized ITO and ITO-Au for electrochemistry of Ce3+/Ce4+ ions.•Redox conversion rates and electrodeposition by cyclic voltammetry and amperometry.•DFT for geometry, energy levels and thermodynamics for Ce-terpyridine complexes.•Thermal CO oxidation and electrochemical CO2 reduction activities were examined.•Interfacial energy level alignment at the interface of ITO-Au and thio-terpyridine.

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关键词

Ce(III,IV) ion,Terpyridine-functionalization,Electrodeposition,Density functional theory,Interfacial energy level,CO/CO2 catalytic interconversion

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