AAl3P6O20 (A = Rb, Cs): Two deep-ultraviolet transparent nonlinear optical materials designed by aliovalent substitution

Journal of Alloys and Compounds(2022)

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摘要
●AAl3P6O20 (A = Rb, Cs) were designed from Ba5P6O20 by aliovalent substitution.●They exhibit the shortest cutoff edges (<190 nm) among Al-based phosphates.●Flexible P3O10 groups are favorable for designing NCS crystal structures.
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关键词
Al-based phosphates,Aliovalent substitution,Short cutoff edge,Nonlinear optical material
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