Identical particles exchange symmetry and the electric dipole moment in molecules

arxiv(2022)

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摘要
Based on fundamental symmetries, molecules cannot have a permanent electric dipole moment although it is commonly used in the literature to explain the different molecular spectra for heteronuclear and homonuclear molecules. Electric-dipole rotational and vibrational spectra can indeed be observed in heteronuclear molecules while they are missing in molecules with identical nuclei. I show that the missing spectral features can be explained as an effect of the exchange symmetry for identical particles.
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关键词
electric dipole moment, molecular spectra, fundamental symmetries, identical particles
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