Synthesis of a covalent organic framework with hydrazine linkages and its application in open-tubular capillary electrochromatography

Journal of Chromatography A(2022)

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摘要
•A well-crystallized hydrazine-linked COF (Tf-DHzOH) was synthesized successfully from 2,5-dihydroxyterephtalohydrazide and 1,3,5-triformyl-benzene.•Tf-DHzOH COF was firstly regarded as a stationary phase material to prepare coated capillary column for open-tubular capillary electrochromatography (OT-CEC).•The separation abilities of Tf-DHzOH coated OT-CEC were evaluated by considering five amino acids, nine sulfonamides and four tetracyclines as analytes.
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关键词
Hydrazine-linked COF,Tf-DHzOH,Capillary electrochromatography,Amino acids,Sulfonamides,Tetracyclines,Benzene compounds
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