Rapid Poling Under Low Direct Current Field Of [001] Oriented Bifeo3-Based Lead-Free Ceramics

SCRIPTA MATERIALIA(2021)

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摘要
[001]-oriented (1- x)BiFeO3-xBaTiO(3)(x = 0.2, 0.3 0.4; BF-BT) ceramics were prepared by templated grain growth (TGG) method. BaTiO3 (BT) templates existed stably in less BF ceramics, resulting in the highest orientation degree (f ) of 72 % for 0.6BiFeO(3)-0.4BaTiO(3). The BaTiO3 templates significantly improved the remanent polarization of samples, indicating that more oriented domain left after removing the electric field. Furthermore, the domain of textured 0.7BiFeO(3)-0.3BaTiO(3) (0.7BFBT-T) switched more quickly and easily than the random one. Therefore, the poling electric field (Ep) of 0.7BFBT-T (2.5 kV/mm) was much lower than reported BF-based samples (4-5 kV/mm). Rapidly poling under low DC field of 0.7BFBT-T was observed, the d 33 value of 0.7BFBT-T reached 96 % when poled at 2.5 kV/mm in 1 min. (C) 2021 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
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关键词
Templated grain growth, Piezoelectric ceramics, BiFeO3
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