Analyzing Nanometer-Thin Cathode Particle Coatings For Lithium-Ion Batteries-The Example Of Tio2 On Ncm622

Cathode active materials (CAMs) in state-of-the-art lithium-ion batteries are mostly lithium-transition-metal oxides such as Li(NixCoyMnz)O-2 (x + y + z = 1). To achieve optimum cycling stability and performance of the cathode, the extent of degradation processes and side reactions between CAMs and liquid or solid electrolytes has to be minimized. For this purpose, various coating strategies for CAMs have been developed in recent years. The underlying mechanism of the protective function of nanoscale coatings and their role for the enhanced cycling performance are mostly unclear, which is often based on incomplete characterization of the coating. Only a few analytical methods, such as X-ray diffraction, scanning electron microscopy/energy-dispersive X-ray analysis, or X-ray photoelectron spectroscopy, have frequently been used in recent years, which often cannot provide enough information for a reliable and consistent picture of the very thin coating. For this reason, we demonstrate a systematic study on the analytical characterization of coated CAM using additional analytical methods. NCM622 coated with TiO2 by atomic layer deposition is used as a model system and analyzed with SEM/EDX, focused ion beam scanning electron microscopy, scanning transmission electron microscopy, Raman spectroscopy, X-ray photoelectron spectroscopy, low-energy ion scattering, and time-of-flight secondary ion mass spectrometry. The results highlight the advantages and disadvantages of each analytical method for the analysis of typical CAM coatings. The results demonstrate that a combination of the different methods is essential to understand CAM coatings and their properties in full detail.