Synthesis, characterization and DFT studies of novel –CH2– capped and non-capped salan complexes

Satabdi Roy,Sudhir Lima,Nadia Ribeiro,Isabel Correia,Fernando Avecilla,Maxim L. Kuznetsov,Joao Costa Pessoa,Werner Kaminsky,Rupam Dinda

Inorganica Chimica Acta（2021）

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摘要

Metal assisted cleavage or non-cleavage of the –CH2– bridge in the salan ligands upon complex formation, as elucidated by structural and spectral characterizations and DFT calculations.

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关键词

Salan,Mononuclear and dinuclear transition metal complexes,Ring cleavage,X-ray structure,DFT

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