Diphenyl-1,3,4-oxadiazoles: synthesis and influence of side chain semifluorination and lateral ring fluorination on liquid crystalline properties
MOLECULAR CRYSTALS AND LIQUID CRYSTALS(2022)
摘要
We present the synthesis and liquid crystalline properties of four sets of diphenyl-1,3,4-oxadiazole based compounds (Sets 1-4). The influence of side chain and lateral fluorinations is discussed. In this study, side chain fluorination (Sets 2 and 3) induces liquid crystalline properties, while lateral fluorination (Set 4) has not induced mesogenic properties. Compounds with either one or two semifluorinated side chains are smectic mesogens (SmC and/or SmA). A comparison among the diphenyl-1,3,4-oxadiazole, biphenylyl-1,3,4-oxadiazole, diphenyl-1,3,4-thiadiazole, and the biphenylyl-1,2,4-oxadiazole cores, which we have previously reported, is discussed.
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关键词
1, 3, 4-Oxadiazoles, smectic liquid crystals, fluorinated liquid crystals, lateral ring fluorination
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