Deducing Mineralogy Of Serpentinized And Carbonated Ultramafic Rocks Using Physical Properties With Implications For Carbon Sequestration And Subduction Zone Dynamics

Serpentinization of ultramafic rocks is fundamental to modern plate tectonics and for volatile (re-)cycling into the mantle and magmatic arcs. Serpentinites are also highly reactive with CO2 such that they are prime targets for carbon sequestration. Serpentinization and carbonation of ultramafic rocks results in changes in their physical properties such that they should be detectable using geophysical surveys; this could provide constraint on the reactivity of rocks without extensive sample characterization. We constrain the physio-chemical relationships in altered ophiolitic ultramafic rocks using petrographic observations, major-element chemistry, quantitative X-ray diffraction, and physical properties on a suite of >400 samples from the Canadian Cordillera. Serpentinization results in a systematic decrease in density that reflects the increase in serpentine abundance and carbonation results in an increase in density, mostly reflecting the formation of magnesite; based on these data, we present two formulations for determining extent of serpentinization: one based on major-element chemistry and the other on density. Magnetic susceptibility is variable during serpentinization; most harzburgitic samples show a 100-fold increase in magnetic susceptibility, whereas most dunitic samples and a minor proportion of harzburgitic samples show very little change in magnetic susceptibility. We use quantitative mineralogy and physical properties of the samples to constrain a model for using density and magnetic susceptibility to approximate the mineralogy of ultramafic rock. Although further work is required to understand the role of remanence in applying these models to geophysical data, this presents an advancement and opportunity to prospect for the most reactive ultramafic rocks for carbon sequestration.