Synthesis Of 2-(Methoxymethyl)Isoindolin-1-Imine Derivatives Via An Unusual Delepine Reaction

Igor Levkov,Andrii Kysil,Angelina Biitseva,Sergey Shilin,Nathalie Saffon-Merceron,Tatyana Yegorova,Zoia V. Voitenko

TETRAHEDRON LETTERS（2021）

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摘要

The synthesis of 2-(methoxymethyl)isoindolin-l-imine derivatives via an unusual Delepine reaction is reported. The substrate substituents' influence on the reaction course was studied, and a possible reaction mechanism proposed. The structure of 2-(methoxymethyl)isoindolin-1-imine was confirmed by X-ray diffraction analysis. (C) 2021 Elsevier Ltd. All rights reserved.

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关键词

2-(methoxymethyl)isoindolin-1-imine, 2-methoxymethyl-2H-isoindo1-1-amine, Delepine reaction, o-Bromomethylbenzonitrile

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