Copper-catalyzed ARGET ATRP of styrene from ethyl α-haloisobutyrate in EtOAc/EtOH, using ascorbic acid/Na2CO3 as reducing system

Marco Borsari,Niccolo Braidi,Mirko Buffagni,Franco Ghelfi,Francesca Parenti,Nicola Porcelli, Gaia Serafini,Abdirisak Ahmed Isse,Luisa Bonifaci,Gianfranco Cavalca,Aldo Longo,Ida Morandini,Nicolo Pettenuzzo

European Polymer Journal（2021）

引用 10|浏览7

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摘要

•“Green” and inexpensive ARGET ATRP for the synthesis of polystyrene.•Chlorine and bromine ATRP systems.•Solvent mixture composed of ethyl acetate and ethanol, even in the presence of modest amounts of H2O.•High yields and low dispersities with low amounts of copper catalyst.

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关键词

Styrene,ARGET ATRP,Copper,Ascorbic acid,Sodium carbonate,Polystyrene

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