An Investigation Of Two Copper(Ii) Complexes With A Triazole Derivative As A Ligand: Magnetic And Catalytic Properties

Yuliia P. Petrenko,Karolina Piasta,Dmytro M. Khomenko,Roman O. Doroshchuk,Sergiu Shova,Ghenadie Novitchi,Yuliya Toporivska,Elzbieta Gumienna-Kontecka,Luisa M. D. R. S. Martins,Rostyslav D. Lampeka

RSC ADVANCES（2021）

引用 14|浏览6

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摘要

Two new copper(ii) complexes [Cu-2(L)(2)(OAc)(2)(H2O)(2)] (1) (L = 3-methyl-5-pyridin-2-yl-1,2,4-triazole) and [CuL2] (2) were prerared and thoroughly studied. The complexes are able to selectively catalyze the oxidation of styrene towards benzaldehyde and of cyclohexane to KA oil. The 2D coordination polymer 1 showed an antiferromagnetic behaviour attributed to the intrachain magnetic coupling.

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