Communication-Self-Doped Mesoporous Activated Carbon Prepared From Car Exhaust Exhibited Long Cycle Life And High Specific Capacitance For Supercapacitor Applications

ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY(2021)

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摘要
We are reporting the preparation of a self-doped mesoporous activated carbon by the treatment of waste collected from car engine exhaust. The waste was pyrolyzed at 850 degrees C in N-2 atmosphere using KOH activating agent. Highly porous activated carbon was obtained with the presence of N, O, S, and P as self-dopant. A high specific surface area of 410 m(2)g(-1) with the pore volume of 0.5947 cm(3)g(-1) was achieved. Electrode prepared with the activated carbon showed a high specific capacitance (280 Fg(-1)) using a 1-butyl-3-methylimidazolium chloride electrolyte. It retained 95% of initial capacitance after 10,000 cycles, demonstrated high cyclic stability and sustainability.
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