Transition-Metal-Catalyzed Stereo- and Regioselective Hydrosilylation of Unsymmetrical Alkynes

Alkyne hydrosilylation is one of the most efficient methods for the synthesis of alkenyl silicon derivatives and has been a hot topic of research for decades. This short review summarizes the progress in transition-metal-catalyzed stereo- and regioselective hydrosilylation of unsymmetrical alkynes. Topics are discussed based on different types of alkynes and the selectivities.