Selective CO2 reduction into formate using Ln–Ta oxynitrides combined with a binuclear Ru(II) complex under visible light

Journal of Energy Chemistry(2021)

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摘要
Ln–Ta oxynitrides with defect fluorite structure were found to serve as effective semiconductor components in visible-light-driven Z-scheme CO2 reduction with a binuclear Ru(II) complex, giving high selectivity to formate (>99%).
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关键词
Artificial photosynthesis,Heterogeneous photocatalysis,Mixed anion compounds,Solar fuels
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