A synergetic effect between photogenerated carriers and photothermally enhanced electrochemical urea-assisted hydrogen generation on the Ni-NiO/Nickel Foam catalyst

The urea-assisted water electrolysis reactions are of great significance for solving the increasingly serious energy crisis and environmental pollution. Recently, the photo-driven effect strategy has been demonstrated to be an efficient external driving force for improving electrocatalytic activities. Herein, we synthesized Ni-NiO heterostructured nanosheet arrays grown on Ni foam (denoted as Ni-NiO/NF) as a bifunctional electrocatalyst enhancing the urea oxidation reaction (UOR) and hydrogen evolution reaction (HER) activities simultaneously under light irradiation. Moreover, when the catalyst is used in a two-electrode system for the urea-assisted water electrolysis reaction, the cell potential could be reduced to 1.48 V to achieve the current density of 10 mA cm(-2) after exposure to light irradiation, as well as remarkable stability. Our studies demonstrate that the enhancement of the HER & UOR activities is attributed to a synergetic effect between photogenerated carriers and photothermy.