Real-Life Emissions From Residential Wood Combustion In Austria: From Tsp Emissions To Pah Emission Profiles, Diagnostic Ratios And Toxic Risk Assessment

Residential wood combustion is, besides particulate emissions, also linked to emissions of organic compounds, comprising various toxic substances such as polycyclic aromatic hydrocarbons (PAHs). Although, literature data has shown that highest emissions occur during maloperations caused by the user itself, most studies focus on labtesting not reflecting the situation in the field. This study evaluates the real-life situation in Austria, investigating emissions of total suspended particles (TSP) and particle-bound substances of four manually operated room heaters commonly installed in people's homes. Measurements were conducted within a field measurement campaign realized in the scope of the Clean Air by biomass project. To evaluate the impact of the users' habit two types of combustion experiments were performed, one representing the diversity of possible maloperations and one realized under optimized conditions following a strict optimization protocol. As special focus was laid on PAHs, sampling was realized using a dilution system adapted for the use in the field. Generally, optimization lead to a clear decrease of most compounds (i.e. TSP, OC, EC, PAHs), however, emissions of the anhydrosugar levoglucosan were not affected at all. Total PAH emissions could be clearly reduced, moreover, optimization lead to a shift towards low molecular weight PAHs and thus, less toxic ones, clearly reflected by lower toxicity equivalents. Correlation analysis using the Spearman's rank method showed significantly high correlations among the individual PAH congeners, and rather low ones with other target substances.