Calix[4]Arene-Based Molecular Photosensitizers For Sustainable Hydrogen Production And Other Solar Applications
CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY(2021)
摘要
This review collects the most representative literature reports on the use of calix[4]arene-based molecules as components, namely photosensitizer dyes, in solar devices, including photovoltaics (dye-sensitized solar cells, DSSC), hydrogen photocatalytic and photoelectrochemical generation from water and sunlight, and CO2 photoreduction. Calix[4]arenes are versatile and easily obtainable scaffolds to be integrated with solar device molecular components either as electron donor groups in pi-conjugated dyes or as host-guest moieties to favor intermolecular interactions. Their beneficial role has been exploited to enhance photovoltaic, hydrogen production, and CO2 reduction performance, paving the way to a new class of molecular active components for next generation solar devices.
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关键词
molecular photosensitizers,sustainable hydrogen production,solar,]arene-based
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