Synthesis of Indolo[2,1‐a]isoquinolin‐6(5H)‐Ones Derivatives via Fe(OTf)3‐Promoted Tandem Selenylation/Cyclization of 2‐Arylindoles

Jia-Rong Zhang,Hao-Yang Liu,Tao Fan,Yan-Yan Chen,Yan-Li Xu

Advanced Synthesis and Catalysis（2021）

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摘要

A practical method for the synthesis of selenylsubstituted indolo[2,1‐a]isoquinolin‐6(5H)‐ones through Fe(OTf)3‐promoted tandem selenylation/cyclization of 2‐arylindoles was developed. In this transformation, new C−Se bond and C−C bond were constructed simultaneously under mild conditions.

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关键词

2-arylindoles,diselenides,Fe(OTf)3-promoted,indolo[2,1-a]isoquinolin-6(5H)-ones,selenylation.

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