V2o5-Activated Graphite Felt With Enhanced Activity For Vanadium Redox Flow Battery

CATALYSTS(2021)

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摘要
In this study, a simple and environment-friendly method of preparing activated graphite felt (GF) for a vanadium redox flow battery (VRFB) by depositing the vanadium precursor on the GF surface and calcining vanadium oxide was explored. The intermediate material, VO2, generated carbon oxidation during the calcination. In contrast to the normal etching method, this method was simple and without a pickling process. On the surface of the activated GF, multiple pores and increased roughness were noted after the calcination temperature and surface area of the activated GF reached 350 degrees C to 400 degrees C and 17.11 m(2)/g, respectively. Additionally, the polarization of the activated GF decreased with resistance to the charge transfer at 0.27 omega. After a single-cell test at current density of 150 mA/cm(2) was performed, the capacity utilization and the capacity retention after 50 cycles reached 70% and 84%, respectively. These results indicated the potential use of activated GF as an VRFB electrode.
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关键词
V2O5, etching, graphite felt, vanadium redox flow battery
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