Chemically functionalized MIL-101-NH2 with cobalt(II) tetrasulfophthalocyanine: an efficient catalyst for the aerobic oxidation of alcohols and one-pot tandem conversion of alcohols to propargylamines

Journal of the Taiwan Institute of Chemical Engineers(2021)

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摘要
•Creation of electrostatic interaction between MIL-101-NH2 and -SO3− group on CoTSPc in water.•MIL-101-NH2/CoTSPc composite as a new and efficient catalyst for the aerobic oxidation of alcohols.•Low-cost and straightforward preparation of catalyst for one-pot tandem conversion of alcohols to propargylamines.•A recyclable and highly stable catalyst for aerobic oxidation of alcohols in the absence of additional oxidant.
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关键词
Metal–organic framework,Aerobic oxidation reaction,Metallophthalocyanines,Heterogeneous catalyst,Tandem oxidation process,A3 coupling reaction
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