The aliphatic ring-opening and SNAr substitution in the reactions of perfluorobenzocycloalkenones with K2CO3 in water and methanol

Journal of Fluorine Chemistry(2021)

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摘要
•Opening of the aliphatic ring of perfluorobenzocycloalken-1-ones in aqueous K2CO3•Synthesis of (2,3,4,5-tetrafluorophenyl)alkanoic acids from benzocycloalken-1-ones•The influence of fluorinated substituents on direction of haloform-type reaction
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关键词
Perfluorinated,Ketone,Ring-opening,Carboxylic acid,Benzocyclobutenone,Indanone,Tetralon
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