Application of task specific ionic liquid for the extraction of Zirconium and Hafnium

Sunita Pathak,Sujoy Biswas,Arijit Sengupta

Journal of Molecular Liquids（2021）

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摘要

•Co-extraction of Zr/Hf by Task Specific Ionic liquid.•Zr formed ML2 complex while Hf formed ML.•Cation exchange mechanism predominates.•Spontaneous, endothermic and entropically driven extraction.•One nitrate ion involved in complexation.

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关键词

Functionalized ionic liquid,Zirconium,Hafmium,Thermodynamics,Gamma irradiation

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