Crystal Structure And Hirshfeld Surface Analysis Of A One-Dimensional Coordination Organic/Inorganic Hybrid [(Moo3)(Biim)](N)

A new one-dimensional organic/inorganic hybrid [(MoO3)(biim)]n has been synthesized by a hydrothermal method in a reactor Parr. Its structure was characterized by FT-IR spectroscopic studies and single-crystal X-ray diffraction. This compound crystallize in the orthorhombic system with space group Cmc2(1), Z = 4, and unit cell parameters a = 6.9834(4) angstrom, b = 9.8771(6) angstrom, c = 13.6740(8) angstrom, and beta, = 103.861(1)((degrees) under bar), V=1026.64(18) angstrom(3). The molecular structure and crystal packing are stabilized mainly by a strong intermolecular hydrogen bonds with atoms N-H center dot center dot center dot O which can be described by graph set symbol R-2(2)(9) and its packing arrangement reinforced by pi-pi stacking. The intercontacts in the crystal structure are analyzed using Hirshfeld surfaces computational method.