Photochromism and photoswitchable luminescence in a Zn-7 cluster-based metal-organic framework with an organic guest

Photochromic materials coupled with photoswitchable luminescence functionalities are of particular interest due to their potential applications in switches and optical memory devices. However, the construction of such materials, especially those with two-color emission states, is still challenging. In this context, a rare Zn-7 cluster-based host-guest MOF material, (bbmp)[Zn-7(IPA)(6)(OH)(4)(H2O)(2)] (1) (H(2)IPA = isophthalic acid, bbmp center dot 2I = 4,4'-([1,1'-biphenyl]-4,4'-diyl)bis(1-methylpyridin-1-ium) diiodide), was prepared by encapsulating an organic cation into an anionic MOF produced from zinc cations and isophthalic acid ligands, which exhibits reversible naked detectable photochromic properties varying from yellow to green upon UV-Vis light irradiation. The photoactive guest bbmp(2+) and the short O center dot center dot center dot N+ distances between the oxygen atoms of the carboxylate groups and the pyridine ring play a crucial role in the photochromism of this compound. More interestingly, the luminescence color of this cluster-based host-guest material can be reversibly switched from green to blue upon irradiation, exhibiting photoswitchable luminescence properties.