[6+3] Annulations of Morita-Baylis-Hillman carbonates and dicyanoheptafulvene
ORGANIC & BIOMOLECULAR CHEMISTRY(2021)
摘要
A [6 + 3] annulation reaction of Morita-Baylis-Hillman carbonates and dicyanoheptafulvene is accomplished by employing commercially available triphenylphosphine as the Lewis base catalyst. A spectrum of densely functionalized bicyclo[4.3.1]decane architectures are efficiently constructed with exclusive diastereoselectivity and good yield (up to 95%).
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