Residual Abundances in GALAH DR3: Implications for Nucleosynthesis and Identification of Unique Stellar Populations

We investigate the [X/Mg] abundances of 16 elements for 82,910 Galactic disk stars from GALAH+ DR3. We fit the median trends of low-Ia and high-Ia populations with a two-process model, which describes stellar abundances in terms of a prompt core-collapse and delayed Type-Ia supernova component. For each sample star, we fit the amplitudes of these two components and compute the residual Delta[X/H] abundances from this two-parameter fit. We find rms residuals less than or similar to 0.07 dex for well-measured elements and correlated residuals among some elements (such as Ba, Y, and Zn) that indicate common enrichment sources. From a detailed investigation of stars with large residuals, we infer that roughly 40% of the large deviations are physical and 60% are caused by problematic data such as unflagged binarity, poor wavelength solutions, and poor telluric subtraction. As one example of a population with distinctive abundance patterns, we identify 15 stars that have 0.3-0.6 dex enhancements of Na but normal abundances of other elements from O to Ni and positive average residuals of Cu, Zn, Y, and Ba. We measure the median elemental residuals of 14 open clusters, finding systematic similar to 0.1-0.4 dex enhancements of O, Ca, K, Y, and Ba and similar to 0.2 dex depletion of Cu in young clusters. Finally, we present a restricted three-process model where we add an asymptotic giant branch star (AGB) component to better fit Ba and Y. With the addition of the third process, we identify a population of stars, preferentially young, that have much higher AGB enrichment than expected from their SNIa enrichment.