Compositional And Morphological Properties Of Platinum-Iridium Electrodeposited On Carbon Fiber Microelectrodes

JOURNAL OF NEURAL ENGINEERING(2021)

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摘要
Objective. Neural interfaces based on carbon fiber (CF) electrodes have demonstrated key positive attributes such as minimal foreign body response and mechanical strength to self-insert in brain tissue. However, carbon does not form a low impedance electrode interface with neural tissue. Electrodeposited platinum iridium (PtIr) has been used to improve electrode interface properties for metallic bioelectrodes. Approach. In this study, a PtIr electrodeposition process has been performed on CF microelectrode arrays to improve the interfacial properties of these arrays. We study the film morphology and composition as well as electrode durability and impedance. Results. A PtIr coating with a composition of 70% Pt, 30% Ir and a thickness of similar to 400 nm was observed. Pt and Ir were evenly distributed within the film. Impedance was decreased by 89% @ 1 kHz. Accelerated soak testing in a heated (T = 50 C-circle) saline solution showed impedance increase (@ 1 kHz) of similar to 12% after 36 days (89 equivalent) of soaking.
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关键词
neural interfaces, carbon fiber microelectrodes, electrode coating, platinum-iridium electrochemical deposition, electron microscopy
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