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Mono-mercapto-functionalized Pillar[5]arene: a Host-Guest Complexation Accelerated Reversible Redox Dimerization.

CHEMICAL COMMUNICATIONS(2021)

Sichuan Univ

Cited 6|Views1
Abstract
A mono-mercapto-functionalized pillar[5]arene and its dimer, capable of being reversibly interconverted, were successfully synthesized. Fascinatingly, a faster reversible redox conversion involving a dynamic disulfide bond was observed between their host-guest complexes compared with the hosts themselves.
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Metal-Organic Frameworks
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