Catalytic properties of supramolecular polymetallated porphyrins

Supramolecular polymetallated pyridylporphyrins have been specially designed for exploring the binding and synergism between the macrocyclic system and the peripheral metal complexes. Their chemistry has been reviewed, focusing on the outstanding behavior in solution or as thin organized films generated with several nanomaterials, for application as molecular devices and in energy conversion processes.