Hydrophobicity and co-solvent effects on Meerwein-Ponndorf-Verley reduction/dehydration cascade reactions over Zr-zeolite catalysts

Hongwei Zhang,Zhan Jiang Quek,Stephan Jaenicke,Gaik-Khuan Chuah

Journal of Catalysis（2021）

引用 16|浏览2

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摘要

•Zr-HY is an excellent catalyst for the cascade reaction.•Hydrophobicity and cosolvents significantly accelerate the title reaction.•Ratio of open:closed Zr sites higher in Zr-HY than Zr-Beta.•IR of sorbed 2-pentanol probes hydrophobic/hydrophilic environment.

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关键词

Zr-zeolites,Confinement effect,Hydrophobicity,Co-solvents,Anethole

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