Gallium-aluminum systematics of marine hydrogenetic ferromanganese crusts: Inter-oceanic differences and fractionation during scavenging

Katharina Schier,David M. Ernst,Isabela Moreno Cordeiro de Sousa,Dieter Garbe-Schönberg,Thomas Kuhn,James R. Hein,Michael Bau

Geochimica et Cosmochimica Acta（2021）

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摘要

•First investigation of Ga-Al systematics by HR-ICP-MS in marine Fe-Mn crusts.•New concentration data for reference materials NOD-P-1, NOD-A-1 and JMn-1.•Ga/Al ratios of Fe-Mn crusts significantly lower than those of ambient seawater.•Fe-Mn crusts record inter-oceanic differences between Ga/Al of seawater.•Significant impact of organic complexes on Ga-Al behavior in seawater.

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关键词

Gallium-aluminum fractionation,Ferromanganese crusts,Solution HR-ICP-MS,Laser ablation HR-ICP-MS,Organic ligands,Critical metals

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