Experimental investigation of the local environment and lattice distortion in refractory medium entropy alloys
Scripta Materialia(2022)
摘要
EXAFS analysis of pure elements, binary and ternary equiatomic refractory alloys within the Nb-Zr-Ti-Hf-Ta system is performed at the Nb and Zr K-edges to analyze the evolution of the chemical local environment and the lattice distortion. A good mixing of the elements is found at the atomic scale. For some compounds, a distribution of distances between the central atom and its neighbors suggests a distortion of the structure. Finally, analysis of the Debye-Waller parameters shows some correlation with the lattice distortion parameter δ², and allows to quantify experimentally the static disorder in medium entropy alloys.
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关键词
Extended X-ray absorption fine structure (EXAFS),Multicomponent alloys,Local environment,Lattice distortion,Refractory
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