Alternating copolymerization of bio-based N-acetylhomocysteine thiolactone and epoxides

Nicolas Illy,Valentin Puchelle,Simon Le Luyer,Philippe Guégan

European Polymer Journal（2021）

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摘要

•Bio-based N-acetylhomocysteine thiolactone was used in anionic copolymerization.•Well-defined alternating poly(ester-alt-thioether)s are synthesized.•Lateral acetamido groups induced large increase of glass transition temperatures.

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关键词

Alternating copolymerization,Anionic ring-opening polymerization,Bio-based γ-thiolactone,Epoxide,Polythioether

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