Calorimetric and spectroscopic studies of interactions of PPI G4 dendrimer with tegafur in aqueous solutions

Adam Buczkowski,Małgorzata Malinowska-Michalak,Artur Stepniak,Pawel Tokarz,Pawel Urbaniak,Bartlomiej Palecz

Journal of Molecular Liquids（2021）

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摘要

•PPI G4 dendrimer binds about 30 molecules of tegafur (TF).•Complexation of PPI G4 with TF is exothermic and occurs spontaneously.•TF molecules are bound with surface part of PPI G4 macromolecules.•Hydrophobic tetrahydrofuran part of TF stabilizes supramolecular complex.

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关键词

PPI G4 dendrimer,Amino-terminated macromolecule,Tegafur,Isothermal titration calorimetry,Equilibrium dialysis, solubility measurements

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