Determination Of Polycyclic Aromatic Hydrocarbons And Their Methylated Derivatives In Sewage Sludge From Northeastern China: Occurrence, Profiles And Toxicity Evaluation

This paper assesses the occurrence, distribution, source, and toxicity of polycyclic aromatic hydrocarbons (PAHs), and their methylated form (Me-PAHs) in sewage sludge from 10 WWTPs in Northeastern China was noted. The concentrations of n-ary sumation PAHs, n-ary sumation Me-PAHs ranged from 567 to 5040 and 48.1 to 479 ng.g(-1)dw, which is greater than the safety limit for sludge in agriculture in China. High and low molecular weight 4 and 2-ring PAHs and Me-PAHs in sludge were prevalent. The flux of sludge PAHs and Me-PAHs released from ten WWTPs, in Heilongjiang province, was calculated to be over 100 kg/year. Principal component analysis (PCA), diagnostic ratios and positive matrix factorization (PMF) determined a similar mixed pyrogenic and petrogenic source of sewage sludge. The average values of Benzo[a]pyrene was below the safe value of 600 ng.g(-1) dependent on an incremental lifetime cancer risk ILCR of 10(-6). Sludge is an important source for the transfer of pollutants into the environment, such as PAHs and Me-PAHs. Consequently, greater consideration should be given to its widespread occurrence.