Interaction of SiCl2 with CO2 in Ar matrices

Sergey E. Boganov,Vladimir M. Promyslov,Pavel G. Shangin,Mikhail A. Syroeshkin,Mikhail P. Egorov

Mendeleev Communications（2021）

引用 3|浏览7

暂无评分

摘要

A 1: 1 photostable complex between dichlorosilylene and CO2 was detected using matrix-isolation FTIR spectroscopy. The photostability can be attributed to the existence of photochemical equilibria between this complex and products of its isomerization, first of all, a complex of dichlorosilanone with CO, which are strongly shifted to the complex. A detailed computational study of the potential energy surface of the SiCl2+CO2 system was carried out.

查看译文

关键词

dichlorosilylene,dichlorosilanone,carbon dioxide,carbon monoxide,donor–acceptor complexes,matrix isolation,FTIR spectroscopy,quantum chemical calculations

AI 理解论文

溯源树

样例

生成溯源树，研究论文发展脉络

Chat Paper

正在生成论文摘要