The Synthesis Of Benzannulated Spiroketals From 1,1-Diacyl-2-Phenylcyclopropanes

Sinan Gai,Jackson S. Henneveld,Andrew P. Cording,Michael P. Badart,Nigel T. Lucas,Bill C. Hawkins

TETRAHEDRON LETTERS（2021）

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摘要

A new method to access benzannulated spiroketals from 1,1-diacyl phenylcyclopropanes is described. The method provides rapid access to 5,5 and 5,6-benzannulated spiroketals in low to moderate yields and with moderate to good diastereoselectivity. (C) 2021 Elsevier Ltd. All rights reserved.

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关键词

Benzannulated spiroketals, Spirocyclization, Spiroketals, Donor-acceptor cyclopropanes

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