Preparation of silicon‐based soybean base oil by modified soybean oil by transesterification and hydrosilation

Xiaobin Zhu,Zhi Yun,Xia Gui

Canadian Journal of Chemical Engineering(2021)

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摘要
A new green lubricating base oil was synthesized from soybean oil and triethyl silane by a combination of transesterification and hydrosilylation. The factors affecting the process of hydrosilylation were thoroughly investigated. AlCl3/C catalyst as catalyst for hydrosilylation showed better catalytic performance, and a higher yield of 36.79% was obtained under optimal condition of molar ratio of transesterified soybean oils/triethyl silane (1:1.1), reaction temperature 120 degrees C, and reaction time 8 h. In addition, the performance of silicon-based soybean base oil was tested according to industry standards. Compared with soybean oil, silicon-based soybean base oil was obtained with high viscosity index, good pour point of -17 degrees C, and excellent wear characteristic.
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关键词
hydrosilylation, pour point, silicon&#8208, based soybean base oil, soybean oil, triethylsilane
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