57Fe Mössbauer Spectroscopic Study on the Fe Doped Supercapacitor Birnessite, $$ ({\text{na}},{\text{k}})_{x} {\text{mn}}^{4 + }_{2 - X} {\text{mn}}^{3 + }_{x} {\text{o}}_{4} \cdot 1.5{\text{h}}_{2} {\text{o}} $$ ( Na , K ) X Mn 2 - X 4 + Mn X 3 + O 4 · 1.5 H 2 O