Tetrabutylammonium fluoride initiated anionic ring-opening polymerizations of N–sulfonyl aziridines

Haixin Wang,Jie Li,Zhenjiang Li,Bo Liu,Kai Chen,Zhihao Zhang,Yongzhu Hu,Fangyuan Zhou,Yongqiang Li,Kai Guo

European Polymer Journal（2020）

引用 7|浏览8

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摘要

•TBAF was the first neutral Ionic pair initiator effect living AROPs of N-sulfonyl aziridines.•Mechanism of initiation by direct attack on the aziridine ring with fluoride and propagation by sulfonyl amidate anion was proposed.•Tetrabutylammonium halide (TBAX) was efficient initiator in anionic ring-opening polymerizations of N-sulfonyl aziridines

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关键词

Anionic,Ring-opening polymerization,N-sulfonyl aziridine,Tetrabutylammonium fluoride

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