Coordination polymers containing a pyrazole-based ligand and 4,4′-bipyridine as a spacer: enhancing the family of nonzero-dimensional compounds featuring single-ion magnetic behavior

Iuri C. Soares,Henrique C.S. Junior,Patrícia S. Vilas Boas de Almeida,Odivaldo C. Alves,Stéphane Soriano,Glaucio B. Ferreira,Guilherme P. Guedes

Inorganic Chemistry Communications（2020）

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摘要

•Two 1D-coordination polymers containing a pyrazole-based ligand and 4,4′-bipy.•Predominant ferromagnetic interactions in the copper-based compound.•ZFS effects are important for magnetic behavior of cobalt(II) polymer.•CASSCF calculations determined the sign of the axial component of the ZFS.•Slow relaxation of the magnetization and a single-ion magnet behavior.

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关键词

Pyrazole,Coordination polymers,Magnetic properties,Crystal structures,Single-ion magnet,Ferromagnetic chain

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