A Novel Titanium Oxycarbide Phase With Metal-Vacancy (Ti1-Ycxo1-X): Structural And Thermodynamic Basis

CERAMICS INTERNATIONAL(2021)

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摘要
A unique phenomenon of TiC?TiO2 reaction at 900 ?C is established, forming a quasi-pure phase of abnormal titanium oxycarbide, since it is commonly synthesized at temperatures above 1500 ?C. Impurity of Magne?li phase (TinO2n-1, 4更多
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关键词
Titanium oxycarbide, Metal-vacancy, Thermodynamic, Solid solution, Structural refinement
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