Synthesis, Characterization and Gas Sensor Application of New Composite Based on MWCNTs:CoPc:Metal Oxide

Baghdad Science Journal(2021)

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摘要
The synthesis of new substituted cobalt Phthalocyanine (CoPc) was carried out using starting materials Naphthalene-1,4,5, tetracarbonic acid dianhydride (NDI) employing dry process method. Metal oxides (MO) alloy of (%60Ni(3)O(4) %40-Co3O4) have been functionalized with multiwall carbon nanotubes (F-MWCNTs) to produce (F-MWCNTs/MO) nanocomposite (E2) and mixed with CoPc to yield (F-MWCNT/CoPc/MO) (E3). These composites were investigated using different analytical and spectrophotometric methods such as H-1-NMR (0-18 ppm), FTIR spectroscopy in the range of (400-4000cm-1), powder X-rays diffraction (PXRD, 2 theta degrees = 10-80), Raman spectroscopy (0-4000 cm-1), and UV-Visible spectrophotometry (0-800 nm). Then the activity of these materials was investigated as a gas sensing of (Ammonia, Methanol and Acetone). For each case, 0.2 mg/.mL of the prepared Copc, Copc/MWCNT, Copc/MWCNTs-MO was dispersed in lm of ammonia, methanol and acetone at 298K. The surface morphology of the prepared materials was heterogeneous.
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关键词
Cobalt phthalocyanine,MWCNTs,Nanocomposite,Gas sensing
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