Single crystal growth, structural characterization and magnetic properties study of an antiferromagnetic trinuclear iron(III) acetate complex with uncoordinated hexamine

Inorganica Chimica Acta(2021)

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摘要
•Novel trinuclear iron(III) acetate as with uncoordinated hexamine.•The complex has been structurally characterized by single crystal X-ray diffraction.•The impact of hexamine on intermolecular interactions was studied.•High-spin iron ions in +3 oxidation state with non-Curie-like behaviour.•Antiferromagnetic interactions between the three individual Fe(III) ions.
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关键词
Single crystal growth,Antiferromagnetism,EPR,SQUID
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