Ruthenium carbamoyl complexes: Coordination chemistry and CO release

Mark A. Wright,Maria A. O’Connell,Joseph A. Wright

Inorganica Chimica Acta（2021）

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摘要

•Reacting Ru(CO)4Br2 with heterocyclic amines leads to ruthenium carbamoyls.•These complexes release CO only when irradiated in the UV.•The metal coordination spheres are similar to the releated iron systems.

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PhotoCORMs,Anti-inflammatory agents,Metal carbonyls

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