Synthesis of B-silylmethyl substituted o- and m-carboranes

Boris A. Izmaylov,Valerii A. Vasnev,Galy D. Markova

Mendeleev Communications（2021）

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摘要

Monosubstituted B-chloro(organyl)silylmethyl-o- and m-carboranes have been synthesized by the reaction of o(m)-carboranes with chloro(chloromethyl)organylsilanes in the presence of AlCl3 at 200–250°C under a pressure of 20–25atm.

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关键词

o(m)-carborane,chloro(chloromethyl)organylsilanes,B-chloro(organo)silyl-o(m)-carboranes,Fridel–Crafts reaction,organosilicon compounds

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