Insight understanding into influence of binding mode of carboxylate with metal ion on ligand-centered luminescence properties in Pb-based coordination polymers

Xusheng Gao,Liduo Zhao,Meijuan Ding,Xiaozu Wang,Lu Zhai,Xiaoming Ren

Chinese Chemical Letters（2021）

引用 6|浏览4

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摘要

Two Pb-based coordination polymers emit room temperature ligand-centered phosphorescence with high quantum yield, which color is strongly dependent on the binding mode of carboxylate with Pb2+ ion.

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关键词

Pb-based coordination polymer,Carboxylate binding mode,Heavy atom effect,Room temperature phosphorescence,Frontier orbital analysis

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